High-Sensitivity NO2 Gas Sensor: Exploiting UV-Enhanced Recovery in a Hexadecafluorinated Iron Phthalocyanine-Reduced Graphene Oxide

Abstract

Monitoring ultralow nitrogen dioxide (NO2) concentrations is crucial for air quality management and public health. However, the existing NO2 gas sensors have several defects, like high cost and power consumption, and exhibit poor selectivity. This study addresses these challenges by presenting a novel hexadecafluorinated iron phthalocyanine-reduced graphene oxide (FePcF16-rGO) covalent hybrid sensor for NO2 detection. This innovative approach, which overcomes the limitations of fabrication cost, energy efficiency, and gas selectivity, is a significant step forward in gas sensor technology. The sensor demonstrates exceptional sensitivity toward ultralow NO2 concentrations (15.14% response for 100 ppb) with a rapid 60 s UV light-induced recovery. Additionally, the sensor exhibits high selectivity for NO2, achieving a limit of detection (LOD) of 8.59 ppb. This approach paves the way for developing cost-effective, energy-efficient, and miniature NO2 monitoring devices for improved environmental monitoring and enhanced safety in workplaces where NO2 exposure is a concern.