Formose reaction controlled by boronic acid compounds

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Abstract

© 2016 Imai et al.; licensee Beilstein-Institut. Formose reactions were carried out in the presence of low molecular weight and macromolecular boronic acid compounds, i.e., sodium phenylboronate (SPB) and a copolymer of sodium 4-vinylphenylboronate with sodium 4-styrenesulfonate (pVPB/NaSS), respectively. The boronic acid compounds provided different selectivities; sugars of a small carbon number were formed favorably in the presence of SPB, whereas sugar alcohols of a larger carbon number were formed preferably in the presence of pVPB/NaSS.

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Imai, T., Michitaka, T., & Hashidzume, A. (2016). Formose reaction controlled by boronic acid compounds. Beilstein Journal of Organic Chemistry, 12, 2668–2672. https://doi.org/10.3762/bjoc.12.263

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