Highly regioselective palladium-catalyzed methoxycarbonylation of styrene using chiral ferrocene- and biphosphole-based ligands

33Citations
Citations of this article
17Readers
Mendeley users who have this article in their library.
Get full text

Abstract

The methoxycarbonylation of styrene has been studied using Pd(OAc)2/L/acid catalytic systems with L being chiral ferrocene- and biphosphole-based ligands. Good activities are obtained in mild conditions. Chemoselectivities and regioselectivities (up to 98% in favour of the branched isomer) are excellent but enantioselectivities remain moderate (ee up to 17%). © 2008 Elsevier Ltd. All rights reserved.

Cite

CITATION STYLE

APA

Diab, L., Gouygou, M., Manoury, E., Kalck, P., & Urrutigoïty, M. (2008). Highly regioselective palladium-catalyzed methoxycarbonylation of styrene using chiral ferrocene- and biphosphole-based ligands. Tetrahedron Letters, 49(35), 5186–5189. https://doi.org/10.1016/j.tetlet.2008.06.057

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free