Ligand design for long-range magnetic order in metal-organic frameworks

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Abstract

We report a class of ligands that are candidates to construct metal-organic frameworks with long-range magnetic order between transition metal centres. Direct quantum chemical calculations predict Néel temperatures exceeding 100 K for the case of Mn.

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Tiana, D., Hendon, C. H., & Walsh, A. (2014). Ligand design for long-range magnetic order in metal-organic frameworks. Chemical Communications, 50(90), 13990–13993. https://doi.org/10.1039/c4cc06433j

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