Mass concentration, optical depth and carbon composition of particulate matter in the major southern West African cities of Cotonou (Benin) and Abidjan (Côte d'Ivoire)

Abstract

Air quality degradation is a major issue in the large conurbations on the shore of the Gulf of Guinea. We present for the first time PM2.5 time series collected in Cotonou, Benin, and Abidjan, Côte d'Ivoire, from February 2015 to March 2017. Measurements were performed in the vicinity of major combustion aerosol sources: Cotonou/traffic (CT), Abidjan/traffic (AT), Abidjan/landfill (AL) and Abidjan/domestic fires (ADF). We report the weekly PM2.5 mass and carbonaceous content as elemental (EC) and organic (OC) carbon concentrations. We also measure the aerosol optical depth (AOD) and the Ångström exponent in both cities. The average PM2.5 mass concentrations were 32 ± 32, 32 ± 24 and 28 ± 19 μg mg-3 at traffic sites CT and AT and landfill site AL, respectively. The domestic fire site shows a concentration of 145 ± 69 μg mg-3 due to the contribution of smoking and roasting activities. The highest OC and EC concentrations were also measured at ADF at 71 ± 29 and 15 ± 9 μg mg-3, respectively, while the other sites present OC concentration between 8 and 12 μg mg-3 and EC concentrations between 2 and 7 μg mg-3. The OC • EC ratio is 4.3 at CT and 2.0 at AT. This difference highlights the influence of two-wheel vehicles using gasoline in Cotonou compared to that of four-wheel vehicles using diesel fuel in Abidjan. AOD was rather similar in both cities, with a mean value of 0.58 in Cotonou and of 0.68 in Abidjan. The seasonal cycle is dominated by the large increase in surface mass concentration and AOD during the long dry season (December-February) as expected due to mineral dust advection and biomass burning activities. The lowest concentrations are observed during the short dry season (August-September) due to an increase in surface wind speed leading to a better ventilation. On the other hand, the high PM2.5 • AOD ratio in the short wet season (October-November) indicates the stagnation of local pollution.