Stereoselective synthesis of (-)-centrolobine

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Abstract

The stereoselective synthesis of (-)-centrolobine has been accomplished starting from d-glyceraldehyde acetonide by a combination of chelation-controlled diastereoselective alkylation and ring-closing metathesis. A high degree of 1,3-asymmetric induction has been realized in an ether system. © 2014 Elsevier Ltd. All rights reserved.

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APA

Yang, Z., & Kim, H. D. (2014). Stereoselective synthesis of (-)-centrolobine. Tetrahedron Asymmetry, 25(4), 305–309. https://doi.org/10.1016/j.tetasy.2013.12.019

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