A study of [Au(ethylenediamine)Cl2]Cl interaction with L-methionine and DL-seleno-methionine by 1H and 13C NMR spectroscopy

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Abstract

The interaction of [Au(en)Cl2]Cl with L-methionine (Met) and DL-seleno-methionine (Se-Met) was carried out in D2O solution at ∼pH 3.8.13C NMR spectra were interpreted by comparison with the spectra recorded after the reaction of Met or Se-Met with HAuCl4and also after oxidation by H2O2. Reactions of [Au(en)Cl2]Cl with Met and Se-Met were found to proceed through the exchange of chloride ligands from complex with Met or Se-Met. Gold(III) reduction takes place during the reaction and en ligand was released from [Au(en)Cl2]Cl complex. © 2010 - IOS Press and the authors. All rights reserved.

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Al-Maythalony, B. A., Wazeer, M. I. M., Isab, A. A., & Ahmad, S. (2010). A study of [Au(ethylenediamine)Cl2]Cl interaction with L-methionine and DL-seleno-methionine by 1H and 13C NMR spectroscopy. Spectroscopy, 24(5), 567–575. https://doi.org/10.3233/SPE-2010-0478

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