Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture

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Abstract

A new microporous porphyrin-based imide linked polymer, PyP, was synthesized in an m-cresol/isoquinoline mixture between a porphyrin and a naphthalene tetra-carboxylic dianhydride.The resultant amorphous polymer demonstrates a moderate surface area (SBET = 428m2 g-1) and CO2 adsorption ability (3.5wt%) and a CO2/CH4 selectivity of 5.6 at 273K/1 bar.

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Neti, V. S. P. K., Wang, J., Deng, S., & Echegoyen, L. (2015). Synthesis of a Polyimide Porous Porphyrin Polymer for Selective CO2 Capture. Journal of Chemistry, 2015. https://doi.org/10.1155/2015/281616

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