Thermal properties of ruthenium alkylidene-polymerized dicyclopentadiene

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Differential scanning calorimetry (DSC) analysis of ring opening methatesis polymerization (ROMP) derived polydicyclopenta-diene (PDCPD) revealed an unexpected thermal behavior. A recurring exothermic signal can be observed in the DSC analysis after an elapsed time period. This exothermic signal was found to be proportional to the resting period and was accompanied by a constant increase in the glass-transition temperature. We hypothesize that a relaxation mechanism within the cross-linked scaffold, together with a long-lived stable ruthenium alkylidene species are responsible for the observed phenomenon. 1469




Vidavsky, Y., Navon, Y., Ginzburg, Y., Gottlieb, M., & Gabriel Lemcoff, N. (2015). Thermal properties of ruthenium alkylidene-polymerized dicyclopentadiene. Beilstein Journal of Organic Chemistry, 11, 1469–1474.

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