Acceptor site recognition of transglycosylase inhibitors A β-D- glucopyranosyl-(1 → 2)-α-D-glucopyranuronamide-derived moenomycin analogue

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Abstract

The synthesis, the antibiotic and the transglycosylase inhibiting properties of a disaccharide analogue of moenomycin A in which the NHAc group of unit E is replaced by a hydroxyl function are described. It can be concluded that this NHAc group is essential for eliciting transglycosylase inhibiting properties, in agreement with a recently established solution structure of moenomycin A.

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Ferse, F. T., Floeder, K., Hennig, L., Findeisen, M., Welzel, P., Müller, D., & Van Heijenoort, J. (1999). Acceptor site recognition of transglycosylase inhibitors A β-D- glucopyranosyl-(1 → 2)-α-D-glucopyranuronamide-derived moenomycin analogue. Tetrahedron, 55(12), 3749–3766. https://doi.org/10.1016/S0040-4020(98)01181-8

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