Alumina-accelerated methanolysis and hydrolysis of acyl and phosphoryl fluorides

  • Posner G
  • Ellis J
  • Ponton J
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Abstract

We have discovered that Woelm chromatographic γ-alumina substantially accelerates hydrolysis (and methanolysis) of acyl and phosphoryl fluorides. Compared to the corresponding homogeneous reactions, these heterogeneous alumina-promoted reactions occur about 250-350 times faster for acyl fluorides and about 1800-3000 times faster for phosphoryl fluorides. © 1981.

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Authors

  • Gary H. Posner

  • Jerry W. Ellis

  • John Ponton

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