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Abstract

We have discovered that Woelm chromatographic γ-alumina substantially accelerates hydrolysis (and methanolysis) of acyl and phosphoryl fluorides. Compared to the corresponding homogeneous reactions, these heterogeneous alumina-promoted reactions occur about 250-350 times faster for acyl fluorides and about 1800-3000 times faster for phosphoryl fluorides. © 1981.

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Posner, G. H., Ellis, J. W., & Ponton, J. (1981). Alumina-accelerated methanolysis and hydrolysis of acyl and phosphoryl fluorides. Journal of Fluorine Chemistry, 19(2), 191–198. https://doi.org/10.1016/S0022-1139(00)81334-2

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