An anomalous mannich reaction of a trimethylsilyl enol ether

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Abstract

Mannich reaction between dimethyl (methylene) ammonium chloride and a silyl enol ether gives a regiochemical result opposite to that obtained from the derived lithium enolate and the same salt. © 1982.

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Danishefsky, S., Kahn, M., & Silvestri, M. (1982). An anomalous mannich reaction of a trimethylsilyl enol ether. Tetrahedron Letters, 23(14), 1419–1422. https://doi.org/10.1016/S0040-4039(00)87122-1

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