Asymmetric induction in mixed [2 + 2] photoadditions. Effect of solvent, alkene concentration and temperature

  • Lange G
  • Decicco C
  • Lee M
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Abstract

In mixed [2 + 2] photoadditions with the chiral auxiliary in either the enone or the alkene component, it was found that changing the polarity of the solvent or the temperature of the irradiation had a marked effect on the extent of asymmetric induction. © 1987.

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Authors

  • Gordon L. Lange

  • Carl Decicco

  • Moses Lee

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