Biomimetic hydroxylation of aromatic compounds: Hydrogen peroxide and manganese-polyhalogenated porphyrins as a particularly good system.

  • Carrier M
  • Scheer C
  • Gouvine P
 et al. 
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Various iron- and manganese-porphyrins were compared as catalysts for the hydroxylation of anisole by H2O2or PhIO. Whereas all the iron-porphyrins tested gave low hydroxylation yields, Mn(III)-meso tetraarylporphyrins bearing halogen substituents on their meso-aryl and pyrrole groups gave good yields (up to 70% based on the oxidant) for the para-hydroxylation of anisole, especially with H2O2as oxidant in the presence of imidazole. Under these conditions, phenanthrene was quantitatively oxidized into its 9,10-epoxide and naphthalene was mainly oxidized into 1-naphthol (40% yield). Hydroxylation yields appeared dependent upon the reactivity of the oxidizing system not only toward the starting aromatic compound but also toward the phenol products. © 1990.

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  • Marie Noelle Carrier

  • Corinne Scheer

  • Pascal Gouvine

  • Jean François Bartoli

  • Pierrette Battioni

  • Daniel Mansuy

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