Carbamate linkers as latent N-methylamines in solid phase synthesis

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Abstract

A new linker strategy for solid phase synthesis has been developed. It utilizes LAH reduction of a carbamate connection to Wang resin which results in N-methylamines, a useful functionality in medicinal chemistry.

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Ho, C. Y., & Kukla, M. J. (1997). Carbamate linkers as latent N-methylamines in solid phase synthesis. Tetrahedron Letters, 38(16), 2799–2802. https://doi.org/10.1016/S0040-4039(97)00510-8

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