Carbamoyl and alkoxycarbonyl complexes of palladium(II) and platinum(II) of the type M(pnp)(CONHR)Cl (pnp = 2,6-bis(diphenylphosphinomethyl)pyridine; M Pd, R C6H5, p-CH3C6H4, p-CH3OC6H4, C6H11, t-Bu; M Pt, R C6H5), Pd(pnp)[CON(Pr)2]Cl (Pr = propyl), M(pnp)(COOR)Cl (M Pd, R C6H5, CH3; M Pt, R CH3), Pd(pnp)(COOCH3)2result from reaction of M(pnp)Cl2with carbon monoxide and amines or alkoxides at room temperature and atmospheric pressure. The carbamoyl complexes react with bases to give urethane or diphenylurea depending upon the experimental conditions. © 1985.
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