Catalytic asymmetric synthesis of substituted benzocyclo-alkenes via the glyoxylate ene reaction

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Abstract

α-Hydroxypropionic ester-substituted-benzocyclo-1,3-hepta-diene, -indene and -3,4-dihydronaphthalenes are produced in 63->99% enantiomeric excess via the (R)-BINOL-TiX2glyoxylate ene reaction. © 1992.

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van der Meer, F. T., & Feringa, B. L. (1992). Catalytic asymmetric synthesis of substituted benzocyclo-alkenes via the glyoxylate ene reaction. Tetrahedron Letters, 33(44), 6695–6696. https://doi.org/10.1016/S0040-4039(00)61022-5

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