Chemoenzymatic polymer-supported liquid phase synthesis of glucose γ-aminobutyric ester

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Abstract

A concise, polymer-supported solution synthesis of 6-O-(γ-aminobutyryl)-D-glucose has been achieved. Glucose was attached to polyethylene glycol monomethyl ether (MPEG) through an α,α′-dioxyxylyl diether linker, and, subsequently, the HO-6 hydroxyl of the glucose was regioselectively esterified with γ-aminobutyric acid by a lipase-catalyzed reaction. © 2003 Elsevier Science Ltd. All rights reserved.

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De Torres, C., & Fernández-Mayoralas, A. (2003). Chemoenzymatic polymer-supported liquid phase synthesis of glucose γ-aminobutyric ester. Tetrahedron Letters, 44(11), 2383–2385. https://doi.org/10.1016/S0040-4039(03)00223-5

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