Chiral carborane-derived thiophosphites: A new generation of ligands for Rh-catalyzed asymmetric hydrogenation

  • Lyubimov S
  • Davankov V
  • Petrovskii P
 et al. 
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Abstract

A new class of chiral monodentate ligands - carborane-containing thiophosphites have been synthesized and tested in the Rh-catalyzed asymmetric hydrogenation of prochiral olefins with the result of up to 99% ee. The dependence of the enantioselectivity on the electronic properties of the carboranyl substituent has been studied. © 2008 Elsevier B.V. All rights reserved.

Author-supplied keywords

  • Asymmetric hydrogenation
  • Carboranes
  • Rhodium
  • Thiophosphite ligands

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Authors

  • Sergey E. Lyubimov

  • Pavel V. Petrovskii

  • Evamarie Hey-Hawkins

  • Andrey A. Tyutyunov

  • Evgeny G. Rys

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