Cumulated trienephosphine oxides. Trapping of an alkylidenecyclopropylidene

  • Santelli-Rouvier C
  • Santelli M
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Abstract

Treatment by BuLi of dibromocarbene adducts on allenic phosphine oxides leads to alkylidenecyclopropylidene that, in one case, is an exceptional stabilized cyclopropylidene: this carbene is trapped by the corresponding cumulated trienephosphine oxide in a bimolecular process. © 1992.

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