Dimethylmalonyltrialkylphosphoranes: Probing the steric effect on phosphorus and its stereochemical consequence in esterification reactions of chiral secondary alcohols

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Abstract

High chemical yields and high levels of stereochemical inversion are demonstrated in the phosphorane-mediated esterification reaction of chiral alcohols with non-hindered carboxylic acids through the incorporation of sterically non-hindered alkyl groups of phosphorus. © 2004 Elsevier B.V. All rights reserved.

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Dyck, J., Zavorine, S., Robertson, A. J., Capretta, A., Larichev, V., Britten, J., & McNulty, J. (2005). Dimethylmalonyltrialkylphosphoranes: Probing the steric effect on phosphorus and its stereochemical consequence in esterification reactions of chiral secondary alcohols. In Journal of Organometallic Chemistry (Vol. 690, pp. 2548–2552). https://doi.org/10.1016/j.jorganchem.2004.10.046

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