Dynamics of orientationally disordered mixed crystal sharing Cl-adamantane and CN-adamantane

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Abstract

Orientationally disordered (OD) mixed crystals formed between cyanoadamantane (CN-A) and chloroadamantane (Cl-A) have been thermodynamically characterized by means of thermal analysis and X-ray diffraction. The dynamics of these OD mixed crystals has been studied by means of broad band dielectric spectroscopy. Results evidence that dynamics of the α-relaxation process associated with the overall molecular tumbling slows down when molecules of CN-A are substituted by molecules of Cl-A. © 2009 Elsevier B.V. All rights reserved.

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Martinez-Garcia, J. C., Capaccioli, S., Diez, S., Tamarit, J. L., Barrio, M., Veglio, N., & Pardo, L. C. (2010). Dynamics of orientationally disordered mixed crystal sharing Cl-adamantane and CN-adamantane. Journal of Non-Crystalline Solids, 356(11–17), 621–624. https://doi.org/10.1016/j.jnoncrysol.2009.04.075

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