Effects of substitution of Bi with Pb in BaBi1-xPbxO3 on crystal structure and conduction behavior

  • Hashimoto T
  • Kawazoe H
  • Shimamura H
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Abstract

The crystal structure of BaBi1-xPbxO3was investigated by X-ray diffraction. In the range 0.0≤x≤0.5, monoclinic symmetry containing two Bi sites was clearly observed. This suggests that Bi exhibits disproportionation to two different chemical states, 3+ and 5+, supplying no electron carrier in the range 0.0≤x

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