An efficient and novel stereoselective protocol for the construction of syn-facially bridged norbornane frameworks

  • Muthusamy S
  • Babu S
  • Gunanathan C
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Abstract

An efficient protocol for the synthesis of syn-facially bridged norbornane frameworks has been developed via tandem cyclization-cycloaddition reactions of rhodium carbenoids generated from α-diazo ketones. Using this new methodology, various functionalized syn-facially bridged norbornane frameworks have been synthesized in a stereoselective manner. © 2002 Elsevier Science Ltd. All rights reserved.

Author-supplied keywords

  • Carbonyl ylides
  • Diazo ketones
  • Dipolar cycloadditions
  • Polynorbornanes
  • Rhodium(II) acetate dimer

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