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Abstract

An efficient protocol for the synthesis of syn-facially bridged norbornane frameworks has been developed via tandem cyclization-cycloaddition reactions of rhodium carbenoids generated from α-diazo ketones. Using this new methodology, various functionalized syn-facially bridged norbornane frameworks have been synthesized in a stereoselective manner. © 2002 Elsevier Science Ltd. All rights reserved.

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Muthusamy, S., Babu, S. A., & Gunanathan, C. (2002). An efficient and novel stereoselective protocol for the construction of syn-facially bridged norbornane frameworks. Tetrahedron Letters, 43(34), 5981–5984. https://doi.org/10.1016/S0040-4039(02)01257-1

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