Low energy (0-6 eV) electron attachment to clusters composed of SF6and N2yields (SF6)n-and anionic complexes containing SF6and N2. The energy profile for the formation of these anions indicates strong contributions due to inelastic electron scattering via the N2-(2Π) resonance followed by intracluster electron transfer. This scattering feature peaks near 2 eV at low stagnation pressure and is shifted to 1.5 eV at 7 bar. The significant shift of the N2-resonance towards lower energy with respect to the gas phase (2.3 eV) is due to the solvation of N2-and the electron transfer behavior between N2-and SF6. © 1995.
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