Enzymatic synthesis of nonracemic inherently chiral calix[4]arenes by lipase-catalysed transesterification

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Abstract

A lipase-catalysed transesterification to effect a desymmetrisation has been used to produce chiral calix[4]arene derivatives with enantiomer excesses (ee) of up to 100%.

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Browne, J. K., McKervey, M. A., Pitarch, M., Russell, J. A., & Millership, J. S. (1998). Enzymatic synthesis of nonracemic inherently chiral calix[4]arenes by lipase-catalysed transesterification. Tetrahedron Letters, 39(13), 1787–1790. https://doi.org/10.1016/S0040-4039(97)10865-6

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