ESR study on π - d correlated molecular salt with benzo group

  • Hayakawa T
  • Kawamata S
  • Hiraoka T
 et al. 
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Abstract

Electron spin resonance (ESR) experiments on (Benzo - TTFVS)2FeBr4have been done with 15.4 GHz microwave by using aligned four single crystals, where Benzo-TTFVS denotes a new donor molecule with benzo group, benzotetrathiafulvalenothioquinone-1,3-dithiolemethide. FeBr4includes Fe(III) d electron spin and an antiferromagnetic ordering occurs below the temperature of TN= 5.8 K. We consider that observed ESR signals originate from d electrons at Fe ions. The shifts in a g-value and the broadening of a line width due to the antiferromagnetic fluctuation are observed at higher temperatures than TN. The g-value and the line width for H | | b are different from those for other directions. The b direction is the direction of the π - d interaction along which donor molecules and counter anions are stacked alternately. These results suggest that the strong fluctuation is related to the π - d correlation. © 2006 Elsevier B.V. All rights reserved.

Author-supplied keywords

  • Electron spin resonance
  • Magnetic phase transition
  • Organic conductor
  • Radical cation salts

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Authors

  • Taro Hayakawa

  • Shuichi Kawamata

  • Takashi Hiraoka

  • Hideki Fujiwara

  • Toyonari Sugimoto

  • Takekazu Ishida

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