Generation and cycloadditions of 2-(N-Acylamino)-1-thia-1,3-dienes. Part II. Rationalization of reactivity using an FMO approach.

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Abstract

2-(N-Acylamino)-1-thia-1,3-dienes undergo regiospecific and stereoselective Diels-Alder cycloaddition to electron deficient, non-activated, and electron rich alkenes to give usefully functionalised dihydrothiopyrans in good yields. © 1989.

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Barnish, I. T., Fishwick, C. W. G., Hill, D. R., & Szanta, C. (1989). Generation and cycloadditions of 2-(N-Acylamino)-1-thia-1,3-dienes. Part II. Rationalization of reactivity using an FMO approach. Tetrahedron, 45(24), 7879–7898. https://doi.org/10.1016/S0040-4020(01)85801-4

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