Helical group 12 co-ordination. The X-ray crystal structure of a five-co-ordinate zinc(II) complex

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Abstract

The templated dimine-containing complexes, [M(SpyNpy2)](ClO4)2·0.5H2O {where M = ZnII, CdIIor HgII}, exhibit chirality in solution (NMR) which is consistent with, and may be diagnostic of, a helical coordination array in these complexes as verified by the X-ray crystal structure of an enantiomer of the zinc(II) derivative. © 1995.

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Adatia, T., Beynek, N., & Murphy, B. P. (1995). Helical group 12 co-ordination. The X-ray crystal structure of a five-co-ordinate zinc(II) complex. Polyhedron, 14(2), 335–338. https://doi.org/10.1016/0277-5387(94)00402-Z

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