Helical group 12 co-ordination. The X-ray crystal structure of a five-co-ordinate zinc(II) complex

  • Adatia T
  • Beynek N
  • Murphy B
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Abstract

The templated dimine-containing complexes, [M(SpyNpy2)](ClO4)2·0.5H2O {where M = ZnII, CdIIor HgII}, exhibit chirality in solution (NMR) which is consistent with, and may be diagnostic of, a helical coordination array in these complexes as verified by the X-ray crystal structure of an enantiomer of the zinc(II) derivative. © 1995.

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Authors

  • Trushar Adatia

  • Nesrin Beynek

  • Brian P. Murphy

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