Highly enantiofacial protonation of prochiral lithium enolates with chiral β-hydroxy sulfoxides

  • Kosugi H
  • Hoshino K
  • Uda H
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Abstract

Highly enantioselective protonation of prochiral lithium enolates is disclosed. The present method employed (S,R(s)) CF3-hydroxy sulfoxide (3b) as the chiral protonating agent, and the protonation or lithium enolates of cyclohexanone derivatives with 3b proceeded with high enantioselectivities.

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Authors

  • Hiroshi Kosugi

  • Kunihide Hoshino

  • Hisashi Uda

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