Indium mediated Barbier reactions of 1,2-diones: A facile synthesis of α-hydroxy ketones

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Abstract

Indium mediated allylation and cinnamylation of 1,2-diones with the corresponding bromides in the presence of sodium iodide produce α-carbonyl homoallylic alcohols in excellent yields. (C) 2000 Elsevier Science Ltd.

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Nair, V., & Jayan, C. N. (2000). Indium mediated Barbier reactions of 1,2-diones: A facile synthesis of α-hydroxy ketones. Tetrahedron Letters, 41(7), 1091–1094. https://doi.org/10.1016/S0040-4039(99)02237-6

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