IR spectroscopy and dynamics of a strongly vibrationally excited polyatomic molecule: CF3I

  • Boyarkin O
  • Ionov S
  • Bagratashvili V
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Abstract

The photodissociation technique was used to measure the linear IR absorption spectrum (ν1and ν4modes) of rotationally jet-cooled CF3I molecules with vibrational energy E≈D≈19000 cm-1, where D is the dissociation threshold. The dissociation yield of CF3I in the molecular beam was determined by resonant multiphoton ionization of atoms. A narrow resonance with a halfwidth γ

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Authors

  • O. V. Boyarkin

  • S. I. Ionov

  • V. N. Bagratashvili

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