Lanthanide assisted cross-coupling of aryl bromides with triethylaluminum

  • Shenglof M
  • Gelman D
  • Molander G
 et al. 
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Abstract

Cerium trichloride, as well as some other lanthanide salts, promote the palladium-catalyzed cross-coupling of triethylaluminum with bromoarenes. The lanthanide compounds also increase the selectivity by diminishing the undesired hydrodebromination process. © 2003 Elsevier Ltd. All rights reserved.

Author-supplied keywords

  • Aluminum
  • Bromoarenes
  • Cross-coupling
  • Lanthanide compounds

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Authors

  • Margarita Shenglof

  • Dmitri Gelman

  • Gary A. Molander

  • Jochanan Blum

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