Liquid-phase oxygenation of hydrocarbons with molecular oxygen catalyzed by Fe2Ni-substituted Keggin-type heteropolyanion

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Abstract

Alkanes such as adamantane, ethylbenzene and cyclohexane, cyclohexene, and aldehydes are selectively oxidized to the corresponding alcohols, ketones, and acids with molecular oxygen alone catalyzed by the Fe(3-x)Ni(x)-substituted Keggin-type heteropolyanion, [PW9O37{Fe(3-x)Ni(x)(OAc)3}](9+x)- (x = predominantly 1). The catalytic activities of [PW9O37{Fe(3-x)Ni(x)(OAc)3}](9+x)- for the oxidation of cyclohexane and butyraldehyde were compared with mono-transition-metal substituted heteropolytungstates and other compounds having oxo-bridged tri-transition-metal sites. In addition, the effects of acetonitrile as a solvent and the addition of isobutyraldehyde were investigated.

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Mizuno, N., Nozaki, C., Hirose, T. O., Tateishi, M., & Iwamoto, M. (1997). Liquid-phase oxygenation of hydrocarbons with molecular oxygen catalyzed by Fe2Ni-substituted Keggin-type heteropolyanion. In Journal of Molecular Catalysis A: Chemical (Vol. 117, pp. 159–168). https://doi.org/10.1016/S1381-1169(96)00293-2

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