New carbonyl tricyclohexylphosphine complexes of ruthenium(II) and osmium(II)

  • Moers F
  • Ten Hoedt R
  • Langhout J
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Abstract

The preparation and properties of a new type of monocarbonyl complex RuCl2(CO)(PCy3)2(PCy3tricyclohexylphosphine) is reported. The reaction of carbon monoxide with RuCl2(CO)(PCy3)2or OxHX(CO)(PCy3)2with X = Cl or Br results in the formation of the complexes RuCl2(CO)2(PCy3)2and OsHX(CO)2(PCy3)2respectively. The preparation and properties of the complexes RuCl(CO)(PCy3)2(CS2H) and OsBr(CO)(PCy3)2(CS2H) are described. © 1974.

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Authors

  • F. G. Moers

  • R. W.M. Ten Hoedt

  • J. P. Langhout

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