New inorganic-organic composite ZnSe(MXDA)1/2

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Abstract

New inorganic-organic hybrid compound was obtained and characterised by powder X-ray diffraction, UV-vis spectroscopy. This nanocomposite material is composed of ZnSe layers and m-xylylenediamine (MXDA) molecules which link inorganic layers. This class of compounds exhibits quantum confinement effect: the optical absorption experiments show that the absorption edge of the title compound exhibits large blue shift. The crystal structure model of ZnSe(MXDA)1/2has been found using direct methods and global optimisation techniques, and refined by the Rietveld method. The title compound crystallises in the orthorhombic crystal system, space group Ccm21(No. 36), Z = 8. Crystal data: a = 6.7346(8) Å, b = 24.9804(2) Å, c = 6.4428(6) Å, and V = 1083.9(2) Å3. © 2007 Elsevier B.V. All rights reserved.

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Gaweł, B., Łasocha, W., & Zieba, M. (2007). New inorganic-organic composite ZnSe(MXDA)1/2. Journal of Alloys and Compounds, 442(1-2 SPEC. ISS.), 77–79. https://doi.org/10.1016/j.jallcom.2006.09.144

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