A new route to cyclic urea derivatives of sugars via phosphinimines

  • Kovács J
  • Pintér I
  • Messmer A
 et al. 
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Abstract

Sugar phosphinimines and the corresponding aminophosphonium salts were prepared from 2-amino-2-deoxy-d-glucosyl azide derivatives and their structures were established by13C- and13P-n.m.r. spectroscopy. A simple one-pot procedure, involving reaction of the azides with triphenylphosphine and carbon dioxide, provides an efficient access to cyclic urea derivatives. © 1987.

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