Nickel-catalyzed multi-component coupling reaction of aldimine, alkyne, and dimethylzinc via dimerization of butadiene

  • Kimura M
  • Togawa M
  • Tatsuyama Y
 et al. 
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Abstract

In the presence of a Ni/phosphine ligand catalyst, dimethylzinc, alkyne, butadiene, aldehyde, and primary amine were successively combined via dimerization of butadiene to provide (3E,7E,10Z)-dodecatrienylamine in good yields with excellent regio and stereoselectivities. © 2009 Elsevier Ltd. All rights reserved.

Author-supplied keywords

  • Aldimine
  • Alkyne
  • Diene
  • Dimethylzinc
  • Nickel

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