Nickel-catalyzed tandem coupling of allyl electrophiles, alkynes, and alkynyltins

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Abstract

The nickel-catalyzed intermolecular coupling of allyl acetate or allyl carbonate with alkynes and alkynyltins was carried out in the presence of LiCl to give 3,6-dien-1-yne regio- and stereoselectively. On the other hand, the intramolecular cyclization and coupling of ω-alkynyl electrophiles with alkynyltins gave five-membered cyclic products.

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APA

Cui, D. M., Tsuzuki, T., Miyake, K., Ikeda, S. I., & Sato, Y. (1998). Nickel-catalyzed tandem coupling of allyl electrophiles, alkynes, and alkynyltins. Tetrahedron, 54(7), 1063–1072. https://doi.org/10.1016/S0040-4020(97)10207-1

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