Nickel-catalyzed tandem coupling of allyl electrophiles, alkynes, and alkynyltins

  • Cui D
  • Tsuzuki T
  • Miyake K
 et al. 
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Abstract

The nickel-catalyzed intermolecular coupling of allyl acetate or allyl carbonate with alkynes and alkynyltins was carried out in the presence of LiCl to give 3,6-dien-1-yne regio- and stereoselectively. On the other hand, the intramolecular cyclization and coupling of ω-alkynyl electrophiles with alkynyltins gave five-membered cyclic products.

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Authors

  • Dong Mei Cui

  • Takao Tsuzuki

  • Kaori Miyake

  • Shin Ichi Ikeda

  • Yoshiro Sato

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