A novel one-dimensional helical chain polymer involving both tetra- and hexacoordinate mercury(II) ions

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Abstract

A new novel one-dimensional (1D) polymer involving both tetra- and hexacoordinate mercury(II) complex, [Hg3(4,4′-bipy)2(CH3COO)2(SCN)4]n, has been synthesized and characterized. The single-crystal X-ray data of the compound show the complex to be an infinite 1D helical chain, two of the Hg atoms are four-coordinate and one is six-coordinate. A new novel one-dimensional (1D) polymer involving both tetra- and hexacoordinate mercury(II) complex, [Hg3(4,4′-bipy)2(CH3COO)2(SCN)4]n, has been synthesized and characterized. The single-crystal X-ray data of the compound show the complex to be an infinite 1D helical chain, two of the Hg atoms are four-coordinate and one is six-coordinate. © 2004 Elsevier B.V. All rights reserved.

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Morsali, A., & Zhu, L. G. (2004). A novel one-dimensional helical chain polymer involving both tetra- and hexacoordinate mercury(II) ions. Inorganic Chemistry Communications, 7(11), 1184–1187. https://doi.org/10.1016/j.inoche.2004.09.003

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