Copolymers of trans-4-hydroxystilbene with (-)menthyl acrylate exhibit upon irradiation transåcis isomerization of the side-chain stilbene chromophores analogously to trans-4-hydroxystilbene-2-methylpropanoate, chosen as low molecular weight model compound. U.v. measurements on polymer samples indicate a deviation from first-order kinetics. In the fluorescence spectra of all-trans polymer samples both excimer and monomer emissions are observed. On irradiation the excimeric component is quenched much faster than the monomeric one. Fluorescence polarization experiments indicate a higher conformational rigidity of the stilbene chromophore when inserted in polymeric systems. Comparison of chiroptical properties of both unirradiated and irradiated copolymers suggests that on irradiation a local conformational rearrangement of macromolecules takes place. © 1983.
Altomare, A., Carlini, C., Ciardelli, F., Solaro, R., Houben, J. L., & Rosato, N. (1983). Photochemistry and photophysics of copolymers of (-)menthyl acrylate with 4-hydroxystilbene acrylate. Polymer, 24(1), 95–100. https://doi.org/10.1016/0032-3861(83)90088-5