Molecular ion centers (XeAr)+in solid Ne were produced by deposition of an ion-containing gas on a cooled substrate. Laser-induced fluorescence (LIF) and excitation yield were studied in the range of transitions between the ground state of the ionic centers and the lower excited states related to the2P1/2,2P3/2limits of Xe+. The fluorescence of (XeAr)+exhibits a vibrational structure with a spacing between the peaks of the fluorescence progression of about ω-e$/ = 11.1 meV.
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