Rate acceleration of phosphoric acid-catalyzed Diels-Alder reaction by internal hydrogen-bonding of adjacent hydroxy group

  • Takagi R
  • Kondo A
  • Ohkata K
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Abstract

The Brønsted acid-catalyzed Diels-Alder reaction was examined. Phosphoric acids were effective Brønsted acids for the Diels-Alder reaction of cyclohexadienones and activated by the internal hydrogen-bonding of the adjacent hydroxy group. © 2007 Elsevier B.V. All rights reserved.

Author-supplied keywords

  • Brønsted acid catalyst
  • Diels-Alder reaction
  • Rate acceleration

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Authors

  • Ryukichi Takagi

  • Asako Kondo

  • Katsuo Ohkata

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