Reactions of the rhenium fragment (η5-C5Me5)Re(CO)2with chlorinated ethylenes: Coordination and C-Cl bond activation

  • Arancibia R
  • Godoy F
  • Garland M
 et al. 
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Abstract

Photochemical reactions of the dinitrogen complex Cp*Re(CO)2N2with tetrachloroethylene and trichloroethylene yield the coordination complexes Cp*Re(CO)2(η2-tetrachloroethy lene) (1) and Cp*Re(CO)2(η2-trichloroethyle ne) (2), respectively. Complex 1 reacts thermally in polar organic solvents to produce the C-Cl bond activation product cis-Cp*Re(CO)2(C2Cl3)C l (3). All complexes were isolated and characterized by IR,1H and13C NMR spectroscopies and mass spectrometry. Complex 3 was also characterized by X-ray crystallography. © 2006 Elsevier B.V. All rights reserved.

Author-supplied keywords

  • C-Cl bond activation: rhenium
  • Chloroethylenes
  • Coordination
  • Pentamethylcyclopentadienyl

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Authors

  • Fernando GodoyUniversity of Santiago de Chile Faculty of Chemistry and Biology

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  • Hugo KlahnPontificia Universidad Catolica de Valparaiso Facultad de Ciencias

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  • Rodrigo Arancibia

  • María Teresa Garland

  • Andrés Ibáñez

  • Ricardo Baggio

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