Reactivity of the alkene component in the ruthenium-catalyzed [2+2] cycloaddition between an alkene and an alkyne: Part 2

  • Jordan R
  • Tam W
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Abstract

Ruthenium-catalyzed [2+2] cycloadditions of 2,3-disubstituted norbornadienes and 2-substituted norbornadienes with an alkyne were found to be highly chemo- and stereoselective with moderate level of regioselectivities and only small rate differences were observed with different substituents on the norbornadiene. © 2002 Elsevier Science Ltd. All rights reserved.

Author-supplied keywords

  • Alkene
  • Alkyne
  • Norbornadiene
  • Ruthenium
  • [2+2] cycloaddition

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Authors

  • Robert W. Jordan

  • William Tam

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