Reductive heterocyclizations via indium/iodine-promoted one-pot conversion of 2-nitroaryl aldehydes, ketones, and imines

  • Han R
  • Son K
  • Ahn G
 et al. 
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Abstract

2-Nitroaryl aldehydes, ketones, and imines were reductively cyclized to 2,1-benzisoxazoles with good yields in the presence of indium and iodine in MeOH. Under a similar condition, N-(2-nitrobenzylidene)anilines were produced mixtures of 2,1-benzisoxazoles and 3-anilino-2-phenyl-2H-indazoles. © 2006 Elsevier Ltd. All rights reserved.

Author-supplied keywords

  • Indium and compounds
  • Nitro compounds
  • Reduction

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Authors

  • Rongbi Han

  • Kee In Son

  • Gil Hwan Ahn

  • Young Moo Jun

  • Byung Min Lee

  • Younbong Park

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