Regioselective alkylation and olefination of allylic carbanion stabilized by two different heteroatoms: Phosphorus and silicon

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Abstract

Treatment of allylphosphonate with LiHMDS, followed by successive addition of chlorotrimethylsilane and carbonyl reagent, afforded dienylsilanes in good yields. 3-Substituted dienylsilanes were obtained by alkylation and olefination of allylic carbanion of 3-trimethylsilylallylphosphonates. © 2001 Elsevier Science Ltd.

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Lee, B. S., Gil, J. M., & Oh, D. Y. (2001). Regioselective alkylation and olefination of allylic carbanion stabilized by two different heteroatoms: Phosphorus and silicon. Tetrahedron Letters, 42(12), 2345–2347. https://doi.org/10.1016/S0040-4039(01)00170-8

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