Regioselective alkylation and olefination of allylic carbanion stabilized by two different heteroatoms: Phosphorus and silicon

  • Lee B
  • Gil J
  • Oh D
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Abstract

Treatment of allylphosphonate with LiHMDS, followed by successive addition of chlorotrimethylsilane and carbonyl reagent, afforded dienylsilanes in good yields. 3-Substituted dienylsilanes were obtained by alkylation and olefination of allylic carbanion of 3-trimethylsilylallylphosphonates. © 2001 Elsevier Science Ltd.

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Authors

  • Bum Sung Lee

  • Jun Mo Gil

  • Dong Young Oh

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