Resonance enhanced multiphoton ionization and time-of-flight mass spectra of jet-cooled 3-chlorophenol dimer

7Citations
Citations of this article
8Readers
Mendeley users who have this article in their library.
Get full text

Abstract

The resonance enhanced multiphoton ionization (REMPI) excitation spectrum of jet-cooled 3-chlorophenol (3-ClP) was measured in combination with time-of-flight (TOF) mass spectrometry. In the TOF mass spectrum, 3-ClP, 3-ClP dimer and 3-ClP-water cluster cations were observed. The REMPI excitation spectrum of the dimer was observed for the first time. The low-frequency intermolecular vibrations show the hydrogen bonding of the dimer of 3-ClP to be similar to the phenol dimer. The hydrogen bonding was found to be weaker than that of the phenol dimer. The structures of the dimer and the 3-ClP-water cluster were obtained from ab initio calculations, which suggest that dimer has a sandwich-type structure with weak hydrogen bond. © 2005 Elsevier B.V. All rights reserved.

Cite

CITATION STYLE

APA

Nakagawa, S., Matsushita, Y., Suzuki, T., & Ichimura, T. (2005). Resonance enhanced multiphoton ionization and time-of-flight mass spectra of jet-cooled 3-chlorophenol dimer. Journal of Molecular Structure, 779(1–3), 68–71. https://doi.org/10.1016/j.molstruc.2004.12.034

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free