Rhodium-catalyzed coupling of sodium tetraphenylborate with acid anhydrides in the presence or absence of norbornene

  • Oguma K
  • Miura M
  • Satoh T
 et al. 
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Abstract

Treatment of sodium tetraphenylborate with aliphatic or aromatic acid anhydrides in the presence of a rhodium catalyst gives the corresponding alkyl (or aryl) phenyl ketones in good yields. In the presence of norbornene, tandem three-component coupling products, 2-acyl-3-phenylnorbornanes are obtained. © 2002 Published by Elsevier Science B.V.

Author-supplied keywords

  • Acid anhydrides
  • Cross-coupling
  • Organoboron compounds
  • Rhodium catalyst

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