(R,R,R)-Tris(2-hydroxy-1-methylethyl)- and (S,S,S)-tris(2-hydroxy-2-methylethyl)phosphine: water-soluble chiral trialkylphosphines with C3-symmetry

  • Kasák P
  • Arion V
  • Widhalm M
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Abstract

The first α- and β-chiral water-soluble trialkylmonophosphines, 1 and 2, respectively, both with C3symmetry, were synthesised from sodium phosphide and chiral mesylates, accessible from (S)-ethyl lactate. X-ray structures of a corresponding 2:1 gold(I) complex [12Au(I)]OTf and of a borane complex 2·BH3were determined. © 2007 Elsevier Ltd. All rights reserved.

Author-supplied keywords

  • Chiral ligands
  • Gold(I) complex
  • Hydroxyphosphines
  • Phosphine borane complexes
  • Sodium phosphide

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